[Ir(COD)2]BF4

Name: [Ir(COD)2]BF4
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 35138-23-9
Cat. No. CS-0082577
Purity≥98%
MDL No.None

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HazMat Fee

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Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

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Structure of 35138-23-9

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Application

[Ir(COD)2]BF4 serves as a well-established precatalyst for iridium-catalyzed hydrogenation and C–H functionalization reactions. Its bench-stable nature and compatibility with a range of substrates enable reliable catalytic activity in asymmetric reductions and selective bond-forming processes. The complex functions effectively in low-loading conditions, facilitating efficient transformations with broad functional group tolerance and predictable reactivity profiles in synthetic workflows.

General Information

CAS No. 35138-23-9
Cat. No. CS-0082577
Purity ≥98%
MDL No. None
Storage -20°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₆H₂₄BF₄Ir
Molecular Weight 495.38
Synonym(s) Bis(1,5-cyclooctadiene)iridium(I)tetrafluoroborate
SMILES FB(F)F.[Ir+].C1/C=C\CC/C=C\C1.C2/C=C\CC/C=C\C2.[F-]

Computational Chemistry Data

TPSA 0
LogP 3.2269
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 0

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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[Ir(COD)2]BF4

CAS No. 35138-23-9

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