Methyl 6-chloro-6-oxohexanoate

Name: Methyl 6-chloro-6-oxohexanoate
Brand: ChemScene
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CAS No. 35444-44-1
Cat. No. CS-0697615
Purity≥95%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Methyl 6-chloro-6-oxohexanoate|CS-0697615

Structure of 35444-44-1

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Description

Methyl 6-chloro-6-oxohexanoate features a chlorinated β-keto ester motif enabling direct functionalization at the α-position. The molecule combines electrophilic reactivity with enhanced stability under standard bench conditions, facilitating efficient carbon–carbon bond formation in synthetic sequences. This compound integrates readily into complex molecular architectures requiring selective ketone and ester handles.

Application

Methyl 6-chloro-6-oxohexanoate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to functionalized carbocycles and heterocycles. Its α,β-unsaturated γ-keto ester motif facilitates Michael additions, aldol reactions, and cyclizations under mild conditions. The chloro group provides a handle for nucleophilic substitution, while the ester moiety supports selective reduction or hydrolysis. Bench-stable and readily purified by distillation or chromatography, it functions reliably in multi-step syntheses of pharmaceutical intermediates and natural product analogs.

General Information

CAS No. 35444-44-1
Cat. No. CS-0697615
Purity ≥95%
MDL No. None
Storage RT, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₁₁ClO₃
Molecular Weight 178.61
Synonym(s) None
SMILES O=C(Cl)CCCCC(=O)OC

Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

Safety Information

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GHS Pictogram :	GHS No : GHS05
Signal Word : Danger	UN#: 3265
Class : 8	Packing Group : Ⅲ
Hazard Statements : H314
Precautionary Statements : P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P363-P405-P501

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Methyl 6-chloro-6-oxohexanoate

CAS No. 35444-44-1

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