3-Bromo-5-nitrobenzaldehyde

Name: 3-Bromo-5-nitrobenzaldehyde
Brand: ChemScene
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CAS No. 355134-13-3
Cat. No. CS-W012968
Purity≥97%
MDL No.MFCD00100097

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 355134-13-3

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Description

3-Bromo-5-nitrobenzaldehyde features a bromine substituent and a nitro group positioned ortho to the aldehyde, creating a highly electron-deficient aromatic ring. This combination enhances reactivity in cross-coupling processes and enables direct functionalization in synthetic sequences requiring strong electrophilic character.

Application

3-Bromo-5-nitrobenzaldehyde serves as a versatile building block in synthetic organic chemistry, enabling direct functionalization via palladium-catalyzed cross-coupling reactions due to its bromo and aldehyde functionalities. The nitro group enhances electrophilicity at the ortho position, facilitating nucleophilic substitution or directed metalation. Its bench-stable crystalline form simplifies handling and purification, making it well-suited for constructing complex heterocycles and pharmaceutical intermediates under standard reaction conditions.

General Information

CAS No. 355134-13-3
Cat. No. CS-W012968
Purity ≥97%
MDL No. MFCD00100097
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₄BrNO₃
Molecular Weight 230.02
Synonym(s) benzaldehyde, 3-bromo-5-nitro-; 3-Bromo-5-nitrobenzaldehyde
SMILES BrC1=CC(=CC(=C1)C=O)[N+](=O)[O-]

Computational Chemistry Data

TPSA 60.21
LogP 2.1698
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 2

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H317-H319-H335
Precautionary Statements : P261-P264-P270-P271-P272-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Other Classifications

Building Blocks Functional Group Nitro compounds

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Bromo-5-nitrobenzaldehyde

CAS No. 355134-13-3

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