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10-Methyl-9-phenylacridinium Perchlorate

  • CAS No. 36519-61-6

  • Cat. No. CS-0105608
  • Purity≥97%
  • MDL No.MFCD09038537

*For research and further manufacturing use only, not for direct human use.

10-Methyl-9-phenylacridinium Perchlorate|CS-0105608

Structure of 36519-61-6

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General Information

  • CAS No. 36519-61-6
  • Cat. No. CS-0105608
  • Purity ≥97%
  • MDL No. MFCD09038537
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₀H₁₆ClNO₄
  • Molecular Weight 369.80
  • Synonym(s) 10-Methyl-9-phenylacridin-10-ium Perchlorate
  • SMILES C[N+]1=C2C=CC=CC2=C(C3=CC=CC=C3)C4=C1C=CC=C4.O=Cl(=O)([O-])=O

Description

10-Methyl-9-phenylacridinium perchlorate is a bench-stable, electron-deficient acridinium salt featuring a phenyl-substituted quaternary nitrogen center. This structure enables efficient photooxidation reactions under visible light, serving as a potent photoredox catalyst in synthetic transformations. The perchlorate counterion enhances solubility in polar organic solvents while maintaining reactivity.

Application

10-Methyl-9-phenylacridinium perchlorate serves as a stable, bench-ready photooxidant enabling efficient aerobic oxidation reactions under visible light. Its rigid acridinium core provides strong electron-accepting character, facilitating single-electron transfer processes with high functional group tolerance. The compound functions effectively in catalytic cycles for C–H activation and heterocycle synthesis, offering clean reaction profiles and straightforward purification due to its crystalline nature and low solubility in nonpolar media.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

  • TPSA   96.12
  • LogP   -0.2715
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   1

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