3-Bromo-4-methylanisole

Name: 3-Bromo-4-methylanisole
Brand: ChemScene
Availability: InStock
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CAS No. 36942-56-0
Cat. No. CS-W003833
Purity≥98%
MDL No.MFCD12547797

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 36942-56-0

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Description

3-Bromo-4-methylanisole features a bromine substituent at the meta position relative to the methoxy group, delivering enhanced reactivity in cross-coupling processes. The para-methyl group imparts steric and electronic modulation, improving selectivity in palladium-catalyzed transformations. This bench-stable aryl halide integrates seamlessly into complex molecule assembly under standard conditions.

Application

3-Bromo-4-methylanisole serves as a versatile aryl building block in medicinal chemistry and process development, enabling palladium-catalyzed cross-coupling reactions such as Suzuki-Miyaura and Stille couplings. Its bromo group exhibits high reactivity under standard conditions, while the methoxy and methyl substituents provide orthogonal functionalization potential and enhanced solubility. The compound demonstrates excellent bench stability and is readily purified by distillation or column chromatography, facilitating integration into multi-step syntheses of bioactive heterocycles and pharmaceutical intermediates.

General Information

CAS No. 36942-56-0
Cat. No. CS-W003833
Purity ≥98%
MDL No. MFCD12547797
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₉BrO
Molecular Weight 201.06
Synonym(s) 2-Bromo-4-methoxy-1-methylbenzene; 3-Bromo-4-methylanisole
SMILES COc1ccc(c(c1)Br)C

Computational Chemistry Data

TPSA 9.23
LogP 2.76612
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Bromo-4-methylanisole

CAS No. 36942-56-0

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