Methyl 3-bromo-5-formylbenzoate

Name: Methyl 3-bromo-5-formylbenzoate
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CAS No. 377734-27-5
Cat. No. CS-0130369
Purity≥95%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Methyl 3-bromo-5-formylbenzoate|CS-0130369

Structure of 377734-27-5

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Description

Methyl 3-bromo-5-formylbenzoate features a bromine atom at the meta position and a formyl group at the para position relative to the methyl ester, enabling orthogonal reactivity. This electron-deficient aromatic scaffold integrates readily into cross-coupling and nucleophilic addition sequences, offering high functional group tolerance under standard conditions.

Application

Methyl 3-bromo-5-formylbenzoate serves as a versatile building block for the synthesis of functionalized aromatic scaffolds. The bromo group enables palladium-catalyzed cross-coupling reactions, while the formyl moiety supports nucleophilic additions and oxime formation. Its methyl ester functionality offers stability and ease of manipulation under standard organic transformations. This compound facilitates efficient access to substituted benzimidazoles, heterocycles, and biaryl systems in medicinal chemistry and materials science applications.

General Information

CAS No. 377734-27-5
Cat. No. CS-0130369
Purity ≥95%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₇BrO₃
Molecular Weight 243.05
Synonym(s) None
SMILES O=C(C1=CC(C=O)=CC(Br)=C1)OC

Computational Chemistry Data

TPSA 43.37
LogP 2.0482
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 2

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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Methyl 3-bromo-5-formylbenzoate

CAS No. 377734-27-5

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