4'-Bromo-4-biphenylboronic acid

Name: 4'-Bromo-4-biphenylboronic acid
Brand: ChemScene
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CAS No. 480996-05-2
Cat. No. CS-W000942
Purity≥98%
MDL No.MFCD02251652

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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4'-Bromo-4-biphenylboronic acid|CS-W000942

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General Information

CAS No. 480996-05-2
Cat. No. CS-W000942
Purity ≥98%
MDL No. MFCD02251652
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₁₀BBrO₂
Molecular Weight None
Synonym(s) boronic acid, B-(4-bromo[1,1-biphenyl]-4-yl)-
SMILES BrC1=CC=C(C2=CC=C(B(O)O)C=C2)C=C1

Description

4'-Bromo-4-biphenylboronic acid features a boronate moiety flanked by a brominated biphenyl system, enabling efficient cross-coupling reactions. This bench-stable reagent integrates seamlessly into Suzuki-Miyaura protocols, delivering high yields in the synthesis of complex biaryl architectures under standard conditions.

Application

4'-Bromo-4-biphenylboronic acid serves as a versatile building block in Suzuki-Miyaura cross-coupling reactions, enabling efficient C–C bond formation under mild conditions. Its stability, ease of handling, and compatibility with diverse functional groups make it ideal for constructing biaryl scaffolds in medicinal chemistry and materials science applications.

Synthesis

Route1
- 121-43-7
- In-stock
  
  92-86-4
- ~41%
- In-stock
  
  480996-05-2
References
- SEMICONDUCTOR ENERGY LABORATORY CO., LTD. Patent: WO2007/29530 A1, 2007 ; Location in patent: Page/Page column 68-69 ;

Safety Information

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Computational Chemistry Data

TPSA 40.46
LogP 1.7959
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 2

Other Classifications

Material Science Material Composite Block Liquid Crystal (LC) Block

Building Blocks Functional Group Boronic Acid And Its Ester

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Chemical Synthesis Organometallic Reagents Organoboron Boronic Acids and Derivatives

Material Science Material Building Blocks Liquid Crystal (LC) Building Blocks Biphenyls

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4'-Bromo-4-biphenylboronic acid

CAS No. 480996-05-2

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