2,6-Dimethyl-4-nitropyridine

Name: 2,6-Dimethyl-4-nitropyridine
Brand: ChemScene
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CAS No. 4913-57-9
Cat. No. CS-0152819
Molecule weight152.15
Purity≥98%
MDL No.MFCD00234324

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 4913-57-9
Cat. No. CS-0152819
Purity ≥98%
MDL No. MFCD00234324
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₈N₂O₂
Molecular Weight 152.15
Synonym(s) None
SMILES CC1=NC(=CC(=C1)[N+](=O)[O-])C

Description

2,6-Dimethyl-4-nitropyridine features a pyridine core with electron-withdrawing nitro and electron-donating methyl groups in strategic positions. This electronic asymmetry enhances its utility in metal coordination and as a building block for functionalized heterocycles. The sterically protected ring system ensures stability under standard conditions, enabling reliable use in synthetic transformations and catalytic applications.

Application

2,6-Dimethyl-4-nitropyridine serves as a versatile building block in synthetic organic chemistry, enabling regioselective functionalization at the 3-position due to electronic deactivation at C2 and C6. Its nitro group facilitates subsequent reduction to an amine or participation in nucleophilic substitution reactions, while the methyl groups enhance stability and influence reactivity profiles. This compound functions effectively in heterocycle synthesis and is valued for its bench stability and compatibility with standard coupling protocols.

Synthesis

Route1
- 4808-64-4
- ~61%
- In-stock
  
  4913-57-9
References
- Zohuri, Gholam Hossein; Seyedi, Seyed Mohammad; Sandaroos, Reza; Damavandi, Saman; Mohammadi, Ali Catalysis Letters, 2010 , vol. 140, # 3-4 p. 160 - 166
Route2
- 108-48-5
- ~%
- In-stock
  
  4913-57-9
References
- Zohuri, Gholam Hossein; Seyedi, Seyed Mohammad; Sandaroos, Reza; Damavandi, Saman; Mohammadi, Ali Catalysis Letters, 2010 , vol. 140, # 3-4 p. 160 - 166

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H320-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 56.03
LogP 1.60664
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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2,6-Dimethyl-4-nitropyridine

CAS No. 4913-57-9

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