[2,2'-Bipyridine]-6,6'-dicarbaldehyde

Name: [2,2'-Bipyridine]-6,6'-dicarbaldehyde
Brand: ChemScene
Availability: InStock
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CAS No. 49669-26-3
Cat. No. CS-0089091
Molecule weightNone
Purity≥97%
MDL No.MFCD06771787

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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[2,2'-Bipyridine]-6,6'-dicarbaldehyde|CS-0089091

Structure of 49669-26-3

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General Information

CAS No. 49669-26-3
Cat. No. CS-0089091
Purity ≥97%
MDL No. MFCD06771787
Storage -20°C, sealed storage, away from moisture
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₈N₂O₂
Molecular Weight None
Synonym(s) 2,2'-Bipyridine-6,6'-dicarbaldehyde
SMILES O=CC1=CC=CC(C2=NC(C=O)=CC=C2)=N1

Description

6,6'-Bipyridine-2,2'-dicarbaldehyde features two aldehyde groups flanking a rigid bipyridine core, enabling coordination to transition metals in diverse geometries. This configuration supports the formation of stable chelates and facilitates applications in catalysis and molecular recognition.

Application

[2,2'-Bipyridine]-6,6'-dicarbaldehyde serves as a versatile bifunctional building block for the synthesis of chelating ligands and metal-organic frameworks. Its dual aldehyde groups enable efficient coupling reactions with amines and hydrazides, facilitating the construction of imine- and hydrazone-based architectures. The molecule exhibits excellent bench stability and is compatible with standard purification protocols, making it well-suited for use in coordination chemistry, catalysis, and functional materials development.

Synthesis

Route1
- In-stock
  
  4411-80-7
- ~62%
- In-stock
  
  49669-26-3
References
- Newkome,G.R.; Leg,H.W. Journal of the American Chemical Society, 1983 , vol. 105, p. 5956
Route2
- In-stock
  
  49669-22-9
- 68-12-2
- ~72%
- In-stock
  
  49669-26-3
References
- Ilyashenko, Gennadiy; Choudhury, Rahela; Motevalli, Majid; Watkinson, Michael Synlett, 2006 , # 11 p. 1759 - 1761
Route3
- In-stock
  
  74065-63-7
- ~57%
- In-stock
  
  49669-26-3
References
- Alzakhem, Nicola; Bischof, Caroline; Seitz, Michael Inorganic Chemistry, 2012 , vol. 51, # 17 p. 9343 - 9349

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 59.92
LogP 1.7686
H_Acceptors 4
H_Donors 0
Rotatable_Bonds 3

Other Classifications

Catalysts and Ligands Ligands Pyridine Ligands Bipyridine Ligands

Material Science Material Building Blocks Covalent Organic Frameworks (COFs) Linkers Aldehyde Linkers

Material Science Polymer/Macromolecule Reagents Covalent Organic Frameworks (COFs) Linkers Aldehyde Linkers

Catalysis Nitrogen-Donor Ligands Pyridine Ligands

Catalysis Nitrogen-Donor Ligands Bipyridine Ligands, Terpyridine Ligands

Key Words

[2,2'-Bipyridine]-6,6'-dicarbaldehyde sigma[2,2'-Bipyridine]-6,6'-dicarbaldehyde manufacturer[2,2'-Bipyridine]-6,6'-dicarbaldehyde price[2,2'-Bipyridine]-6,6'-dicarbaldehyde structure[2,2'-Bipyridine]-6,6'-dicarbaldehyde SDSbuy [2,2'-Bipyridine]-6,6'-dicarbaldehyde[2,2'-Bipyridine]-6,6'-dicarbaldehyde supplier[2,2'-Bipyridine]-6,6'-dicarbaldehyde uses[2,2'-Bipyridine]-6,6'-dicarbaldehyde molecular weightprice of [2,2'-Bipyridine]-6,6'-dicarbaldehyde[2,2'-Bipyridine]-6,6'-dicarbaldehyde chemical name formula of [2,2'-Bipyridine]-6,6'-dicarbaldehyde

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[2,2'-Bipyridine]-6,6'-dicarbaldehyde

CAS No. 49669-26-3

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