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CS-W001157 4
Total: USD 88.00

Tris(dibenzylideneacetonyl)bis-palladium

  • CAS No. 51364-51-3

  • Cat. No. CS-W020210
  • Purity≥97%
  • MDL No.MFCD00013310
  • HazMat Fee +

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    Type
    HazMat Fee
    Excepted Quantity $0.00
    FedEx Limited Quantities Ground $0.00
    Hazmat Ground shipping $50.00+
    Inaccessible (Haz class 6.1 or 9), Domestic $68.00+
    Accessible (Haz class 3, 4, 5 or 8), Domestic $158.00+
    Inaccessible (Haz class 6.1 or 9), International $108.00+
    Accessible (Haz class 3, 4, 5 or 8), International $238.00+

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*For research and further manufacturing use only, not for direct human use.

Tris(dibenzylideneacetonyl)bis-palladium|CS-W020210

Structure of 51364-51-3

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Description

Tris(dibenzylideneacetone)dipalladium(0) (Pd2(dba)3) is a versatile compound widely used as a Pd(0) source in various Pd-mediated transformations. Pd2(dba)3 is known for its high reactivity and ability to facilitate oxidative addition reactions. It is prepared by reacting palladium salts with dibenzylideneacetone ligands. It acts as a catalyst for several reactions including Suzuki cross-coupling, Heck coupling, arylation, Buchwald-Hartwig amination, and fluorination. It is often used in catalytic amounts and has been shown to be effective in promoting coupling reactions between aryl halides and boronic acids.For small scale and high throughput uses, product is also available as ChemBeads (919772)Application Guide for Palladium Catalyzed Cross-Coupling ReactionsReactant involved in: Synthesis of azepanes Synthesis of nanosized palladium phosphides upon interaction with white phosphorous Preparation of palladium triphenylphosphine carbonyl cluster complexes Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynesCatalyst for: Suzuki cross-coupling reactions PCN- and PCS-pincer palladium complex catalyzed tandem allylation Catalyst for Suzuki coupling of aryl chlorides (eq. 1) Catalyst for Heck coupling of aryl chlorides (eq. 2) Catalyst for arylation of ketones (eq. 3) Catalyst for Buchwald-Hartwig amination of aryl halides (eq. 4) Catalyst for fluorination of allylic chlorides (eq. 5) Catalyst for -arylation of carboxylic esters (eq. 6) Catalyst for carbonylation of 1,1-dichloro-1-alkenes (eq. 7) Catalyst for conversion of aryl and vinyl triflates to aryl and vinyl halides (eq. 8) Pd source for enantioselective Tsuji Allylations

General Information

  • CAS No. 51364-51-3
  • Cat. No. CS-W020210
  • Purity ≥97%
  • MDL No. MFCD00013310
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₅₁H₄₂O₃Pd₂
  • Molecular Weight 915.71
  • Synonym(s) None
  • SMILES O=C(/C=C/C1=CC=CC=C1)/C=C/C2=CC=CC=C2.[Pd][Pd].O=C(/C=C\C3=CC=CC=C3)/C=C\C4=CC=CC=C4.O=C(/C=C\C5=CC=CC=C5)/C=C\C6=CC=CC=C6

Computational Chemistry Data

  • TPSA   17.07
  • LogP   3.9773
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   4

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07,GHS08
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H317-H411
Precautionary Statements : P261-P261-P272-P272-P273-P280-P280-P302+P352-P302+P352

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