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Structure of 51364-51-3
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Tris(dibenzylideneacetone)dipalladium(0) (Pd2(dba)3) is a versatile compound widely used as a Pd(0) source in various Pd-mediated transformations. Pd2(dba)3 is known for its high reactivity and ability to facilitate oxidative addition reactions. It is prepared by reacting palladium salts with dibenzylideneacetone ligands. It acts as a catalyst for several reactions including Suzuki cross-coupling, Heck coupling, arylation, Buchwald-Hartwig amination, and fluorination. It is often used in catalytic amounts and has been shown to be effective in promoting coupling reactions between aryl halides and boronic acids.For small scale and high throughput uses, product is also available as ChemBeads (919772)Application Guide for Palladium Catalyzed Cross-Coupling ReactionsReactant involved in: Synthesis of azepanes Synthesis of nanosized palladium phosphides upon interaction with white phosphorous Preparation of palladium triphenylphosphine carbonyl cluster complexes Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynesCatalyst for: Suzuki cross-coupling reactions PCN- and PCS-pincer palladium complex catalyzed tandem allylation Catalyst for Suzuki coupling of aryl chlorides (eq. 1) Catalyst for Heck coupling of aryl chlorides (eq. 2) Catalyst for arylation of ketones (eq. 3) Catalyst for Buchwald-Hartwig amination of aryl halides (eq. 4) Catalyst for fluorination of allylic chlorides (eq. 5) Catalyst for -arylation of carboxylic esters (eq. 6) Catalyst for carbonylation of 1,1-dichloro-1-alkenes (eq. 7) Catalyst for conversion of aryl and vinyl triflates to aryl and vinyl halides (eq. 8) Pd source for enantioselective Tsuji Allylations
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GHS Pictogram :
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GHS No : GHS07,GHS08
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H317-H411
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Precautionary Statements : P261-P261-P272-P272-P273-P280-P280-P302+P352-P302+P352
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Lot numbers can be found on the outside label of a product: