1-Bromo-2-chloro-4-iodobenzene

Name: 1-Bromo-2-chloro-4-iodobenzene
Brand: ChemScene
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CAS No. 535934-25-9
Cat. No. CS-W005077
Molecule weight317.35
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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1-Bromo-2-chloro-4-iodobenzene|CS-W005077

Structure of 535934-25-9

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General Information

CAS No. 535934-25-9
Cat. No. CS-W005077
Purity ≥97%
MDL No. None
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₃BrClI
Molecular Weight 317.35
Synonym(s) 3-chloro-4-bromo-iodobenzene
SMILES ClC1=CC(I)=CC=C1Br

Description

1-Bromo-2-chloro-4-iodobenzene features three halogens positioned for selective cross-coupling reactions. The ortho-chloro and para-iodo substituents enable sequential functionalization, while the bromo group provides a stable handle under palladium catalysis. This trihalogenated aromatic serves as a precision scaffold in complex molecule assembly.

Application

1-Bromo-2-chloro-4-iodobenzene serves as a versatile trihalogenated benzene building block for palladium-catalyzed cross-coupling reactions. Its orthogonal halogen reactivity enables sequential functionalization, facilitating the construction of complex biaryl and heteroaryl scaffolds. The molecule exhibits excellent bench stability and is compatible with standard reaction conditions, allowing efficient access to substituted arenes in medicinal chemistry and materials science applications.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 0
LogP 3.7071
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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1-Bromo-2-chloro-4-iodobenzene

CAS No. 535934-25-9

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