3-Bromo-2-chloro-5-nitropyridine

Name: 3-Bromo-2-chloro-5-nitropyridine
Brand: ChemScene
Availability: InStock
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CAS No. 5470-17-7
Cat. No. CS-D0768
Purity≥98%
MDL No.MFCD00233989

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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3-Bromo-2-chloro-5-nitropyridine|CS-D0768

Structure of 5470-17-7

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General Information

CAS No. 5470-17-7
Cat. No. CS-D0768
Purity ≥98%
MDL No. MFCD00233989
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₅H₂BrClN₂O₂
Molecular Weight 237.44
Synonym(s) NSC 26278; 2-Chloro-3-bromo-5-nitropyridine
SMILES O=[N+](C1=CN=C(Cl)C(Br)=C1)[O-]

Description

3-Bromo-2-chloro-5-nitropyridine features a tri-substituted pyridine core with complementary halogen and nitro functionalities, enabling selective cross-coupling and functionalization in late-stage diversification. The electron-deficient ring facilitates nucleophilic substitution under mild conditions, while the orthogonal reactivity of bromo and chloro groups allows sequential transformations. This scaffold delivers high stability and predictable regiochemistry in synthetic workflows.

Application

3-Bromo-2-chloro-5-nitropyridine serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling selective cross-coupling reactions via its halogen substituents. The nitro group provides a handle for reduction to an amine, while the ortho-halogen arrangement facilitates controlled functionalization. Its bench-stable nature and compatibility with Pd-catalyzed coupling protocols make it well-suited for modular heterocycle construction and late-stage diversification in API development.

Synthesis

Route1
- In-stock
  
  15862-33-6
- ~93%
- In-stock
  
  5470-17-7
References
- Synthesis, , # 6 p. 499 - 501

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS05,GHS06
Signal Word : Danger	UN#: 2811
Class : 6.1	Packing Group : Ⅲ
Hazard Statements : H301-H318
Precautionary Statements : P264-P270-P280-P330-P405-P501

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Computational Chemistry Data

TPSA 56.03
LogP 2.4057
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Nitro compounds

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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3-Bromo-2-chloro-5-nitropyridine

CAS No. 5470-17-7

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