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CS-W001157 4
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Tetramethylammonium hexafluorophosphate

  • CAS No. 558-32-7

  • Cat. No. CS-0185872
  • Molecule weight219.11
  • Purity≥98%
  • MDL No.MFCD00012012

*For research and further manufacturing use only, not for direct human use.

Tetramethylammonium hexafluorophosphate|CS-0185872

Structure of 558-32-7

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General Information

  • CAS No. 558-32-7
  • Cat. No. CS-0185872
  • Purity ≥98%
  • MDL No. MFCD00012012
  • Storage 4°C, sealed storage, away from moisture
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₄H₁₂F₆NP
  • Molecular Weight 219.11
  • Synonym(s) None
  • SMILES C[N+](C)(C)C.F[P-](F)(F)(F)(F)F

Description

Tetramethylammonium (hexafluorophosphate) serves as a highly soluble, bench-stable source of tetramethylammonium cations in synthetic organic chemistry. This salt features a non-coordinating anion that minimizes interference in polar reaction environments. It facilitates phase-transfer catalysis and enables efficient ion exchange processes under standard conditions.

Application

Tetramethylammonium (hexafluorophosphate) serves as a mild, bench-stable source of tetramethylammonium cations in synthetic transformations. It functions effectively in phase-transfer catalysis and facilitates nucleophilic substitutions under neutral conditions. The hexafluorophosphate counterion enhances solubility in organic media while minimizing side reactions, making it well-suited for scale-up and purification in complex synthesis workflows.

Synthesis

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      Tetramethylammonium hexafluorophosphate|CS-0185872
      558-32-7

    References

    • Z. anorg. allg. Chem., , vol. 263, p. 253 - 260 P: MVol.C, 178, page 409 - 412
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      16921-91-8
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      999-77-9
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      Tetramethylammonium hexafluorophosphate|CS-0185872
      558-32-7

    References

    • Z. anorg. allg. Chem., , vol. 263, p. 253 - 260 P: MVol.C, 178, page 409 - 412
  • Route3
    • null|null
      16921-91-8
    • In-stock
      Tetramethylammonium iodide|CS-W015577
      75-58-1
    • ~%
    • In-stock
      Tetramethylammonium hexafluorophosphate|CS-0185872
      558-32-7

    References

    • Z. anorg. allg. Chem., , vol. 263, p. 253 - 260 P: MVol.C, 178, page 409 - 412

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: 2811
Class : 6.1
Packing Group : Ⅲ
Hazard Statements : H302-H312-H315-H319-H332-H335
Precautionary Statements : P260-P261-P264-P270-P271-P280-P301+P310-P302+P352-P304+P340-P304+P341-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362+P364-P363-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   0
  • LogP   3.7048
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   0

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