Tris(1,10-phenanthroline)ruthenium(II) hexafluorophosphate

Name: Tris(1,10-phenanthroline)ruthenium(II) hexafluorophosphate
Brand: ChemScene
Availability: InStock
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CAS No. 60804-75-3
Cat. No. CS-0084759
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Tris(1,10-phenanthroline)ruthenium(II) hexafluorophosphate|CS-0084759

Structure of 60804-75-3

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General Information

CAS No. 60804-75-3
Cat. No. CS-0084759
Purity ≥97%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₆H₂₄F₁₂N₆P₂Ru
Molecular Weight 931.61
Synonym(s) Tris(1,10-phenanthroline)ruthenium(II) Bis(hexafluorophosphate)
SMILES [N]1([Ru+2]234([N]5=CC=CC6=C5C7=[N]4C=CC=C7C=C6)[N](C=CC=C8C=C9)=C8C%10=C9C=CC=[N]%103)=C(C%11=[N]2C=CC=C%11C=C%12)C%12=CC=C1

Description

Tris(1,10-phenanthroline)ruthenium(II) hexafluorophosphate delivers a highly stable, water-soluble complex with intense red-orange luminescence. This tris-chelated ruthenium(II) species features three bidentate phenanthroline ligands that enhance photochemical durability and electronic coupling. The hexafluorophosphate counterion improves solubility in polar solvents and supports use in electrochemical studies and luminescent sensing applications.

Application

Tris(1,10-phenanthroline)ruthenium(II) hexafluorophosphate serves as a robust, air-stable photoredox catalyst enabling efficient single-electron transfer processes in organic synthesis. Its well-defined redox properties facilitate C–H functionalization, cross-coupling, and heterocycle formation under mild conditions. The hexafluorophosphate counterion enhances solubility in organic media and simplifies purification, making it ideal for scalable bench applications.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

Other Classifications

Catalysts and Ligands Catalysts Photocatalysts Ruthenium Series Photocatalysts

Material Science Electronic Materials Organic Light-Emitting Diode (OLED) Materials Light Emitters and Dopants

Catalysis Photocatalysts

Catalysis Compounds by Element Classes Metal Compounds Transition Metal Compounds

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Tris(1,10-phenanthroline)ruthenium(II) hexafluorophosphate

CAS No. 60804-75-3

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