(2-Bromophenyl)diphenylphosphine

Name: (2-Bromophenyl)diphenylphosphine
Brand: ChemScene
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CAS No. 62336-24-7
Cat. No. CS-0095833
Purity≥95%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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(2-Bromophenyl)diphenylphosphine|CS-0095833

Structure of 62336-24-7

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Description

(2-Bromophenyl)diphenylphosphine is a sterically hindered phosphine reagent featuring a brominated aryl group that enables direct functionalization in cross-coupling reactions. This bench-stable, moisture-tolerant ligand integrates seamlessly into palladium-catalyzed transformations, delivering high yields with minimal decomposition under standard conditions.

Application

(2-Bromophenyl)diphenylphosphine serves as a versatile phosphine ligand in palladium-catalyzed cross-coupling reactions, enabling efficient C–C bond formation under mild conditions. Its ortho-bromo substituent facilitates downstream functionalization via further coupling or cyclization, enhancing its utility in constructing complex aryl architectures. The molecule exhibits good bench stability and is compatible with standard purification protocols, making it well-suited for iterative synthetic sequences in medicinal chemistry and materials science applications.

General Information

CAS No. 62336-24-7
Cat. No. CS-0095833
Purity ≥95%
MDL No. None
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₈H₁₄BrP
Molecular Weight 341.18
Synonym(s) Diphenyl(2-bromophenyl)phosphine
SMILES BrC1=CC=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3

Computational Chemistry Data

TPSA 0
LogP 4.2073
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 3

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302
Precautionary Statements : P264-P270-P330-P501

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(2-Bromophenyl)diphenylphosphine

CAS No. 62336-24-7

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