5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III) chloride

Name: 5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III) chloride
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CAS No. 62769-24-8
Cat. No. CS-0160247
Purity≥97%
MDL No.MFCD09038959

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III) chloride|CS-0160247

Structure of 62769-24-8

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General Information

CAS No. 62769-24-8
Cat. No. CS-0160247
Purity ≥97%
MDL No. MFCD09038959
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄₈H₃₆ClMnN₄O₄
Molecular Weight 823.23
Synonym(s) Chloromanganese(III) meso-tetra(p-methoxyphenyl)porphyrin
SMILES [Cl-][Mn+3]123[N]=4C=5C=CC4C(C=6C=CC(OC)=CC6)=C7C=CC(=C(C8=CC=C(OC)C=C8)C=9C=CC(=C(C%10=CC=C(OC)C=C%10)C%11=CC=C(C5C=%12C=CC(OC)=CC%12)[N-]%111)[N]92)[N-]73

Description

This manganese(III) porphyrin features four 4-methoxyphenyl groups at the meso positions, enhancing solubility and stability in organic media. The electron-donating methoxy substituents modulate redox potential, while the chloride counterion ensures charge balance. Designed for catalytic oxidation studies, this complex exhibits robust performance under ambient conditions and serves as a well-defined model for biological oxidations.

Application

5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III) chloride serves as a stable, bench-ready porphyrin-based catalyst for oxidation reactions. Its four 4-methoxyphenyl groups enhance solubility and electronic modulation, enabling efficient oxygen transfer in epoxidation and C–H functionalization processes. The manganese(III) center provides robust catalytic activity under mild conditions, with good functional group tolerance and ease of handling—ideal for scalable synthetic workflows and mechanistic studies.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

Other Classifications

Catalysts and Ligands Catalysts Transition Metal Catalysts Mn Catalysts

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Catalysis Non-Precious Metal Catalysis

Catalysis Asymmetric Synthesis Chiral Catalysts, Chiral Ligands, Chiral Reagents Chiral Catalysts (Other)

Catalysis C-H Activation Manganese Compounds

Catalysis Compounds by Element Classes Metal Compounds Transition Metal Compounds

Catalysis Transition Elements Manganese

Key Words

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5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III) chloride

CAS No. 62769-24-8

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