3-Chloro-5-methoxyphenol

Name: 3-Chloro-5-methoxyphenol
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CAS No. 65262-96-6
Cat. No. CS-D1537
Purity≥98%
MDL No.MFCD00002260

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 65262-96-6

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Description

3-Chloro-5-methoxyphenol features a phenolic hydroxyl group flanked by electron-withdrawing chlorine and electron-donating methoxy substituents, creating a uniquely polarized aromatic system. This structural motif enables direct participation in cross-coupling reactions and facilitates incorporation into bioactive scaffolds requiring balanced electronic properties. The compound exhibits enhanced solubility in organic solvents compared to unsubstituted phenols and maintains stability under standard bench conditions.

Application

3-Chloro-5-methoxyphenol serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling efficient access to functionalized aromatic scaffolds. Its ortho-chloro and para-methoxy substituents provide predictable reactivity in palladium-catalyzed cross-coupling reactions and allow for selective derivatization via electrophilic substitution or nucleophilic displacement. The compound exhibits good bench stability and facilitates straightforward purification, making it well-suited for iterative synthetic campaigns requiring reliable functional group compatibility.

General Information

CAS No. 65262-96-6
Cat. No. CS-D1537
Purity ≥98%
MDL No. MFCD00002260
Storage RT, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇ClO₂
Molecular Weight 158.58
Synonym(s) 65262-96-6
SMILES OC1=CC(OC)=CC(Cl)=C1

Computational Chemistry Data

TPSA 29.46
LogP 2.0542
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Chloro-5-methoxyphenol

CAS No. 65262-96-6

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