2-Bromo-3-nitroanisole

Name: 2-Bromo-3-nitroanisole
Brand: ChemScene
Availability: InStock
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CAS No. 67853-37-6
Cat. No. CS-W001123
Purity≥97%
MDL No.MFCD07779272

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

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Structure of 67853-37-6

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Description

2-Bromo-3-nitroanisole features a strategically positioned bromine atom and nitro group flanking a methoxy-substituted aromatic ring, enabling direct functionalization in cross-coupling reactions. This electron-deficient aryl halide integrates readily into complex molecular architectures under standard conditions.

Application

2-Bromo-3-nitroanisole serves as a versatile building block in synthetic organic chemistry, enabling palladium-catalyzed cross-coupling reactions due to its well-defined halogen functionality. The nitro group provides strong electron-withdrawing character, enhancing reactivity in nucleophilic substitution and facilitating downstream functionalization. Its methoxy substituent offers orthogonal handle for selective transformations, while the molecule exhibits excellent bench stability and ease of purification—making it a reliable intermediate in the synthesis of complex heterocycles and pharmaceutical scaffolds.

General Information

CAS No. 67853-37-6
Cat. No. CS-W001123
Purity ≥97%
MDL No. MFCD07779272
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₆BrNO₃
Molecular Weight 232.03
Synonym(s) 2-Bromo-3-nitrophenyl methyl ether
SMILES O=[N+](C1=C(Br)C(OC)=CC=C1)[O-]

Computational Chemistry Data

TPSA 52.37
LogP 2.3659
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 2

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Bromo-3-nitroanisole

CAS No. 67853-37-6

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