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CS-W001157 4
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N-Boc-Imino-(triphenyl)phosphorane

  • CAS No. 68014-21-1

  • Cat. No. CS-W005769
  • Molecule weight377.42
  • Purity≥97%
  • MDL No.MFCD00798174

*For research and further manufacturing use only, not for direct human use.

N-Boc-Imino-(triphenyl)phosphorane|CS-W005769

Structure of 68014-21-1

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General Information

  • CAS No. 68014-21-1
  • Cat. No. CS-W005769
  • Purity ≥97%
  • MDL No. MFCD00798174
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₃H₂₄NO₂P
  • Molecular Weight 377.42
  • Synonym(s) N-Boc-imino(triphenyl)phosphorane
  • SMILES O=C(N=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)OC(C)(C)C

Description

N-Boc-Imino-(triphenyl)phosphorane delivers a stable, bench-ready phosphorus ylide for stereoselective olefination reactions. The Boc-protected imino group enables controlled nitrogen incorporation, while the triphenylphosphine scaffold ensures high reactivity and ease of handling under standard conditions.

Application

N-Boc-Imino-(triphenyl)phosphorane serves as a stable, bench-ready reagent for the synthesis of imines and enamines via phosphorus ylide-mediated transformations. Its Boc-protected imino group enables selective N-functionalization while maintaining compatibility with diverse functional groups. The triphenylphosphine moiety facilitates efficient Wittig-type olefination and heterocycle formation, offering high chemoselectivity and ease of purification in complex molecule assembly.

Synthesis

  • Route1
    • null|null
      1070-19-5
    • null|null
      603-35-0
    • ~94%
    • In-stock
      N-Boc-Imino-(triphenyl)phosphorane|CS-W005769
      68014-21-1

    References

    • Journal of Organic Chemistry, , vol. 58, # 18 p. 4791 - 4793
  • Route2
    • null|null
      117672-39-6
    • null|null
      865-47-4
    • ~59%
    • In-stock
      N-Boc-Imino-(triphenyl)phosphorane|CS-W005769
      68014-21-1

    References

    • Organic Letters, , vol. 7, # 4 p. 713 - 716
  • Route3
    • null|null
      603-35-0
    • ~%
    • In-stock
      N-Boc-Imino-(triphenyl)phosphorane|CS-W005769
      68014-21-1

    References

    • Organic Letters, , vol. 7, # 4 p. 713 - 716

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05
Signal Word : Danger
UN#: 1759
Class : 8
Packing Group : Ⅲ
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   38.66
  • LogP   5.0992
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   3

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