2-Chloro-1,10-phenanthroline

Name: 2-Chloro-1,10-phenanthroline
Brand: ChemScene
Availability: InStock
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CAS No. 7089-68-1
Cat. No. CS-W004568
Purity≥97%
MDL No.MFCD00185678

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 7089-68-1

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Description

2-Chloro-1,10-phenanthroline is a bench-stable, electron-deficient heterocyclic ligand featuring a chlorinated aromatic system that enhances metal coordination affinity. This derivative integrates readily into transition metal complexes, offering improved solubility and stability in polar solvents. Its para-chloro substitution facilitates downstream functionalization and enables precise tuning of redox properties in catalytic systems.

Application

2-Chloro-1,10-phenanthroline serves as a versatile ligand in transition metal catalysis, enabling efficient cross-coupling and oxidation reactions. Its chlorinated derivative offers enhanced reactivity in Pd-catalyzed transformations while maintaining bench stability and ease of purification. Functions effectively in the synthesis of metallorganic complexes and heterocyclic scaffolds relevant to medicinal chemistry and materials science.

General Information

CAS No. 7089-68-1
Cat. No. CS-W004568
Purity ≥97%
MDL No. MFCD00185678
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₇ClN₂
Molecular Weight None
Synonym(s) Chlorophenanthroline
SMILES ClC1=NC2=C3C(C=CC=N3)=CC=C2C=C1

Computational Chemistry Data

TPSA 25.78
LogP 3.4364
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

Safety Information

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GHS Pictogram :	GHS No : GHS07,GHS05
Signal Word : Danger	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H318-H335-H412
Precautionary Statements : P260-P264-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P310-P312-P330-P332+P313-P362+P364-P403+P233-P405-P501

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Other Classifications

Catalysts and Ligands Ligands Pyridine Ligands Phenanthroline Ligands

Material Science Material Building Blocks Ligands for Functional Metal Complexes Phenanthroline Ligands

Catalysis Nitrogen-Donor Ligands Pyridine Ligands

Catalysis Nitrogen-Donor Ligands Phenanthroline Ligands

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2-Chloro-1,10-phenanthroline

CAS No. 7089-68-1

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