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CS-W001157 4
Total: USD 88.00

3-Bromobenzo[b]thiophene

  • CAS No. 7342-82-7

  • Cat. No. CS-W005311
  • Molecule weight213.09
  • Purity≥97%
  • MDL No.MFCD00023009

*For research and further manufacturing use only, not for direct human use.

3-Bromobenzo[b]thiophene|CS-W005311

Structure of 7342-82-7

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General Information

  • CAS No. 7342-82-7
  • Cat. No. CS-W005311
  • Purity ≥97%
  • MDL No. MFCD00023009
  • Storage 4°C, protect from light
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₈H₅BrS
  • Molecular Weight 213.09
  • Synonym(s) 3-bromothianaphthene
  • SMILES BrC1=CSC2=C1C=CC=C2

Description

3-Bromothianaphthene is a heteroaryl halide. It undergoes Suzuki-Miyaura reaction with phenylboronic acid (PBA) or 3-thienylboronic acid in the presence of a novel heterogeneous Pd catalyst [Pd@PDEB, PDEB=poly(1,3-diethynylbenzene)]. The substitution reaction of 3-bromothianaphthene with piperidine to form 3-piperidinothianaphthene as the major product has been reported.3-Bromothianaphthene may be used in the synthesis of (benzo[b]thiophen-3-yl)trimethylstannane.

Synthesis

  • Route1

    References

    • Dit Chabert, Jeremie Fournier; Joucla, Lionel; David, Emilie; Lemaire, Marc Tetrahedron, 2004 , vol. 60, # 14 p. 3221 - 3230
  • Route2

    References

    • Chelucci, Giorgio; Baldino, Salvatore; Ruiu, Andrea Journal of Organic Chemistry, 2012 , vol. 77, # 21 p. 9921 - 9925,5
  • Route3

    References

    • Tetrahedron, , vol. 63, # 2 p. 356 - 362

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   0
  • LogP   3.6638
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   0

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