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2-(Bromomethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol

  • CAS No. 7465-44-3

  • Cat. No. CS-0535942
  • Molecule weight257.08
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

2-(Bromomethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol|CS-0535942

Structure of 7465-44-3

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General Information

  • CAS No. 7465-44-3
  • Cat. No. CS-0535942
  • Purity ≥98%
  • MDL No. None
  • Storage Sealed in dry,2-8℃
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₇H₁₃BrO₅
  • Molecular Weight 257.08
  • Synonym(s) Methyl 6-deoxy-6-brom-alpha-D-glucopyranoside
  • SMILES COC1C(C(C(C(O1)CBr)O)O)O

Synthesis

  • Route1

    References

    • Nakane, Masami; Hutchinson, C. Richard; Gollman, Harold Tetrahedron Letters, 1980 , vol. 21, p. 1213 - 1216
  • Route2
    • 2-(Bromomethyl)-4,5-dihydroxy-6-methoxytetrahydro-2H-pyran-3-yl benzoate|CS-0535944
      10368-81-7
    • ~%
    • 2-(Bromomethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol|CS-0535942
      7465-44-3

    References

    • Crout, David H. G.; Hanrahan, Jane R.; Hutchinson, David W. Carbohydrate Research, 1993 , vol. 239, # 1 p. 305 - 308
  • Route3
    • 2-(Bromomethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triyl triacetate|CS-0535943
      7404-32-2
    • ~%
    • 2-(Bromomethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol|CS-0535942
      7465-44-3

    References

    • Helferich et al. Chemische Berichte, 1926 , vol. 59, p. 79,83

Safety Information

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GHS Pictogram : N/A
GHS No : N/A
Signal Word : N/A
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : N/A
Precautionary Statements : N/A

Quality Control

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Computational Chemistry Data

  • TPSA   79.15
  • LogP   -1.1647
  • H_Acceptors   5
  • H_Donors   3
  • Rotatable_Bonds   2

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