3-Bromo-2-nitrophenol

Name: 3-Bromo-2-nitrophenol
Brand: ChemScene
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CAS No. 76361-99-4
Cat. No. CS-0042077
Purity≥97%
MDL No.MFCD08445675

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

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Structure of 76361-99-4

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Description

3-Bromo-2-nitrophenol features a bromine substituent at the meta position relative to a nitro group on a phenolic scaffold. This electron-deficient aromatic system enables direct functionalization in cross-coupling reactions and serves as a key intermediate in pharmaceutical synthesis. The compound exhibits stability under standard bench conditions and facilitates selective derivatization through its reactive hydroxyl and halogen moieties.

Application

3-Bromo-2-nitrophenol serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling direct functionalization at the phenolic hydroxyl group while retaining ortho-directed reactivity. Its bromine and nitro substituents facilitate subsequent cross-coupling reactions and electrophilic substitution processes under standard conditions. The compound exhibits good bench stability and is readily purified by recrystallization, making it suitable for scale-up applications.

General Information

CAS No. 76361-99-4
Cat. No. CS-0042077
Purity ≥97%
MDL No. MFCD08445675
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₄BrNO₃
Molecular Weight 218.00
Synonym(s) 2-Nitro-3-bromophenol
SMILES OC1=CC=CC(Br)=C1[N+]([O-])=O

Computational Chemistry Data

TPSA 63.37
LogP 2.0629
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS05,GHS07,GHS09
Signal Word : Danger	UN#: 3077
Class : 9	Packing Group : Ⅲ
Hazard Statements : H302-H315-H317-H318-H410
Precautionary Statements : P261-P264-P270-P272-P273-P280-P302+P352-P330-P362+P364-P391-P501

Quality Control

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Other Classifications

Building Blocks Functional Group Nitro compounds

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Bromo-2-nitrophenol

CAS No. 76361-99-4

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