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CS-W001157 4
Total: USD 88.00

(-)-Fenchone

  • CAS No. 7787-20-4

  • Cat. No. CS-0032516
  • Purity≥98%
  • MDL No.MFCD00151104

*For research and further manufacturing use only, not for direct human use.

(-)-Fenchone|CS-0032516

Structure of 7787-20-4

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General Information

  • CAS No. 7787-20-4
  • Cat. No. CS-0032516
  • Purity ≥98%
  • MDL No. MFCD00151104
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₁₆O
  • Molecular Weight None
  • Synonym(s) None
  • SMILES O=C1[C@](C2)(C)CC[C@]2([H])C1(C)C

Description

(1R)-(-)-Fenchone is a bridged bicyclic ketone found in fennel oil and thuja oil.(1R)-(-)-Fenchone undergoes condensation with pyridinylalkylamines to form chiral iminopyridine ligands, which find applications in enantioselective copper-catalyzed Henry (nitro aldol) reaction. It may also be used in the preparation of enantiopure C(7)-anti-substituted fenchones as new chiral sources.

Synthesis

  • Route1

    References

    • Chemical and Pharmaceutical Bulletin, , vol. 59, # 12 p. 1570 - 1573
  • Route2
    • null|null
      74163-80-7
    • ~84%
    • In-stock
      (-)-Fenchone|CS-0032516
      7787-20-4

    References

    • Journal of Chemical Research, , # 7 p. 411 - 414
  • Route3
    • null|null
      89050-88-4
    • ~%
    • In-stock
      (-)-Fenchone|CS-0032516
      7787-20-4

    References

    • Journal of Photochemistry and Photobiology A: Chemistry, , vol. 218, # 1 p. 41 - 47

Safety Information

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GHS Pictogram :
GHS No : GHS02
Signal Word : Warning
UN#: 1993
Class : 3
Packing Group : Ⅲ
Hazard Statements : H226
Precautionary Statements : P210-P233-P240-P370+P378-P303+P361+P353-P403+P235-P501

Quality Control

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Computational Chemistry Data

  • TPSA   17.07
  • LogP   2.4017
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   0

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