4-(4-Bromophenylsulfonyl)morpholine

Name: 4-(4-Bromophenylsulfonyl)morpholine
Brand: ChemScene
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CAS No. 834-67-3
Cat. No. CS-0208443
Molecule weight306.18
Purity≥98%
MDL No.MFCD00194739

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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4-(4-Bromophenylsulfonyl)morpholine|CS-0208443

Structure of 834-67-3

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General Information

CAS No. 834-67-3
Cat. No. CS-0208443
Purity ≥98%
MDL No. MFCD00194739
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₁₂BrNO₃S
Molecular Weight 306.18
Synonym(s) 4-bromo-N-morpholinylbenzenesulfonamide
SMILES C1=C(C=CC(=C1)S(=O)(=O)N2CCOCC2)Br

Description

4-(4-Bromophenylsulfonyl)morpholine features a brominated phenylsulfonyl group attached to a morpholine ring, enabling efficient coupling in cross-coupling reactions. This electron-deficient aryl sulfonyl moiety integrates readily into pharmaceutical scaffolds and serves as a stable, bench-stable building block for synthetic medicinal chemistry.

Application

4-(4-Bromophenylsulfonyl)morpholine serves as a versatile building block in medicinal chemistry, enabling efficient construction of sulfonamide-containing heterocycles. Its bromine substituent facilitates palladium-catalyzed cross-coupling reactions, while the morpholine ring offers solubility and metabolic stability advantages. The compound exhibits excellent bench stability and compatibility with standard synthetic protocols, making it well-suited for iterative library synthesis and API development.

Synthesis

Route1
- 110-91-8
- 98-58-8
- ~97%
- In-stock
  
  834-67-3
References
- Bioorganic and Medicinal Chemistry Letters, , vol. 17, # 14 p. 3880 - 3885
Route2
- 110-91-8
- 20846-02-0
- ~90%
- In-stock
  
  834-67-3
References
- WO2004/20401 A1, ; Page 9 ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302
Precautionary Statements : P264-P270-P330-P501

Quality Control

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Computational Chemistry Data

TPSA 46.61
LogP 1.47
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aliphatic heterocycle compounds Morpholine compounds

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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4-(4-Bromophenylsulfonyl)morpholine

CAS No. 834-67-3

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