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CS-W001157 4
Total: USD 88.00

1-Hexyl-3-methylimidazolium Bromide

  • CAS No. 85100-78-3

  • Cat. No. CS-W009303
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

1-Hexyl-3-methylimidazolium Bromide|CS-W009303

Structure of 85100-78-3

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General Information

  • CAS No. 85100-78-3
  • Cat. No. CS-W009303
  • Purity ≥98%
  • MDL No. None
  • Storage 4°C, sealed storage, away from moisture
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₁₉BrN₂
  • Molecular Weight 247.18
  • Synonym(s) 1-hexyl-3-MethyliMidazoliuM briMide
  • SMILES C[N+]1=CN(CCCCCC)C=C1.[Br-]

Description

1-Hexyl-3-methylimidazolium bromide is a room-temperature liquid ionic compound featuring a hydrophobic hexyl chain and a positively charged imidazolium core. This combination imparts excellent solubility in organic media while maintaining strong ionic character, enabling its use as a stable, non-volatile electrolyte or reaction medium in catalysis and electrochemistry.

Application

1-Hexyl-3-methylimidazolium bromide serves as a stable, bench-ready ionic liquid that facilitates homogeneous catalysis and phase-transfer processes. Its imidazolium core enables efficient metal coordination and stabilizes reactive intermediates, while the long alkyl chain enhances solubility in organic media. The bromide anion provides good nucleophilicity and compatibility with common transition metal catalysts, making it suitable for cross-coupling reactions, C–H functionalization, and electrochemical applications.

Synthesis

  • Route1
    • In-stock
      1-Methylimidazole|CS-W008580
      616-47-7
    • null|null
      111-25-1
    • ~99%
    • In-stock
      1-Hexyl-3-methylimidazolium Bromide|CS-W009303
      85100-78-3

    References

    • Wilms, Daniel; Klos, Johannes; Kilbinger, Andreas F. M.; Loewe, Holger; Frey, Holger Organic Process Research and Development, 2009 , vol. 13, # 5 p. 961 - 964
  • Route2
    • null|null
      111-25-1
    • null|null
      5587-42-8
    • ~84%
    • In-stock
      1-Hexyl-3-methylimidazolium Bromide|CS-W009303
      85100-78-3

    References

    • Sorm, Miloslav; Nespurek, Stanislav; Prochazka, Miloslav; Koropecky, Igor Collection of Czechoslovak Chemical Communications, 1983 , vol. 48, # 1 p. 103 - 111
  • Route3
    • null|null
      74-83-9
    • In-stock
      1-Hexylimidazole|CS-0152141
      33529-01-0
    • ~%
    • In-stock
      1-Hexyl-3-methylimidazolium Bromide|CS-W009303
      85100-78-3

    References

    • Collection of Czechoslovak Chemical Communications, , vol. 48, # 1 p. 103 - 111

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

Quality Control

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Computational Chemistry Data

  • TPSA   8.81
  • LogP   -1.1031
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   5

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