(2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) hexafluorophosphate

Name: (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) hexafluorophosphate
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CAS No. 864163-80-4
Cat. No. CS-0087750
Molecule weight873.70
Purity≥95%
MDL No.MFCD29472513

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(2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) hexafluorophosphate|CS-0087750

Structure of 864163-80-4

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General Information

CAS No. 864163-80-4
Cat. No. CS-0087750
Purity ≥95%
MDL No. MFCD29472513
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₂H₂₀F₁₀IrN₄P
Molecular Weight 873.70
Synonym(s) Ir[(dFppy)2(bpy)]PF6
SMILES FC(C=C(F)C=C12)=C1C3=CC=CC=[N]3[Ir+]452([N]6=CC=CC=C6C7=[N]5C=CC=C7)[N]8=CC=CC=C8C9=C4C=C(F)C=C9F.F[P-](F)(F)(F)(F)F

Description

This iridium(III) complex features a chelating bipyridine ligand paired with two fluorinated pyridine units, delivering enhanced electron-withdrawing character and improved charge transport. The hexafluorophosphate counterion ensures high solubility in polar organic solvents, enabling efficient integration into OLED emissive layers.

Application

This iridium(III) complex serves as a highly efficient phosphorescent emitter in OLED applications, leveraging the robust chelation of bipyridine and difluorophenylpyridine ligands to enhance thermal and photochemical stability. The hexafluorophosphate counterion ensures high solubility and charge balance, enabling facile incorporation into device architectures. Its strong emission in the green-to-yellow region is attributed to metal-to-ligand charge transfer transitions, making it a reliable building block for next-generation display technologies.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

Other Classifications

Catalysts and Ligands Catalysts Photocatalysts Iridium Series Photocatalysts

Material Science Electronic Materials Organic Light-Emitting Diode (OLED) Materials Light Emitters and Dopants

Catalysis Compounds by Element Classes Metal Compounds Transition Metal Compounds

Catalysis Photocatalysts

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(2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) hexafluorophosphate

CAS No. 864163-80-4

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