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CS-W001157 4
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IPrAgCl

  • CAS No. 873297-19-9

  • Cat. No. CS-0099045
  • Molecule weight531.92
  • Purity≥95%
  • MDL No.MFCD15072152

*For research and further manufacturing use only, not for direct human use.

IPrAgCl|CS-0099045

Structure of 873297-19-9

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General Information

  • CAS No. 873297-19-9
  • Cat. No. CS-0099045
  • Purity ≥95%
  • MDL No. MFCD15072152
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₇H₃₆AgClN₂
  • Molecular Weight 531.92
  • Synonym(s) None
  • SMILES Cl[Ag]=C1N(C=CN1C=2C(=CC=CC2C(C)C)C(C)C)C=3C(=CC=CC3C(C)C)C(C)C

Description

Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver features a sterically shielded N-heterocyclic carbene ligand that stabilizes the silver center, enabling robust reactivity in catalytic transformations. The bulky diisopropylphenyl groups confer exceptional bench stability and moisture tolerance, facilitating handling under standard laboratory conditions. This complex integrates seamlessly into cross-coupling and functionalization protocols where precise metal-ligand interactions are critical.

Application

Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver serves as a stable, bench-ready silver(I) source for C–H functionalization and cross-coupling reactions. Its N-heterocyclic carbene ligand imparts enhanced stability and functional group tolerance, enabling efficient transformations under mild conditions. The complex facilitates selective silver-mediated coupling processes with broad applicability in synthetic organic chemistry workflows.

Safety Information

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GHS Pictogram : N/A
GHS No : N/A
Signal Word : N/A
UN#: N/A
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Packing Group : N/A
Hazard Statements : N/A
Precautionary Statements : N/A

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Computational Chemistry Data

  • TPSA   9.86
  • LogP   8.52989
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   6

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