3-Bromo-1-[tris(propan-2-yl)silyl]-1H-pyrrole

Name: 3-Bromo-1-[tris(propan-2-yl)silyl]-1H-pyrrole
Brand: ChemScene
Availability: InStock
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CAS No. 87630-36-2
Cat. No. CS-0038939
Purity≥95%
MDL No.MFCD01321136

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Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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3-Bromo-1-[tris(propan-2-yl)silyl]-1H-pyrrole|CS-0038939

Structure of 87630-36-2

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Description

This tris(tert-butyl)silyl-protected pyrrole delivers enhanced stability and solubility in organic media, enabling reliable use in cross-coupling reactions. The bulky silyl group prevents undesired side reactions while the bromo substituent provides a reactive handle for palladium-catalyzed transformations.

Application

3-Bromo-1-[tris(propan-2-yl)silyl]-1H-pyrrole serves as a stable, bench-ready building block for the synthesis of functionalized pyrroles. The tris(propan-2-yl)silyl group provides exceptional steric protection and enhances solubility, enabling efficient purification and compatibility with palladium-catalyzed cross-coupling reactions. Its bromine substituent facilitates diverse transformations including Suzuki-Miyaura, Stille, and Negishi couplings, making it a versatile scaffold for constructing complex heterocyclic architectures in medicinal chemistry and materials science.

General Information

CAS No. 87630-36-2
Cat. No. CS-0038939
Purity ≥95%
MDL No. MFCD01321136
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₃H₂₄BrNSi
Molecular Weight None
Synonym(s) Bromotriisopropylsilylpyrrole
SMILES CC(C)[Si](C(C)C)(C(C)C)N1C=CC(=C1)Br

Computational Chemistry Data

TPSA 4.93
LogP 5.2742
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 4

Safety Information

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GHS Pictogram : N/A	GHS No : N/A
Signal Word : N/A	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : N/A
Precautionary Statements : N/A

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Other Classifications

Building Blocks Functional Group Organosilicon compounds

Building Blocks Skeleton Aromatic heterocycle compounds Pyrrole compounds

Material Science Organic-Inorganic Hybrid Materials A silane coupling agent

Key Words

87630-36-2 sigma87630-36-2 manufacturer87630-36-2 price87630-36-2 structure87630-36-2 SDSbuy 87630-36-287630-36-2 supplier87630-36-2 uses87630-36-2 molecular weightprice of 87630-36-287630-36-2 chemical name formula of 87630-36-2

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3-Bromo-1-[tris(propan-2-yl)silyl]-1H-pyrrole

CAS No. 87630-36-2

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