Methyl 4-fluoropicolinate

Name: Methyl 4-fluoropicolinate
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CAS No. 886371-79-5
Cat. No. CS-0176103
Purity≥96%
MDL No.None

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Type	HazMat Fee
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FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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General Information

CAS No. 886371-79-5
Cat. No. CS-0176103
Purity ≥96%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₆FNO₂
Molecular Weight 155.13
Synonym(s) Methyl 4-fluoropyridine-2-carboxylate
SMILES COC(C1=NC=CC(F)=C1)=O

Description

Methyl 4-fluoropicolinate is a bench-stable, electron-deficient heterocyclic ester featuring a para-fluorinated pyridine ring. This structural motif enables efficient coupling in cross-coupling reactions and serves as a key building block in medicinal chemistry. The fluorine substituent enhances metabolic stability and modulates electronic properties for targeted molecular design.

Application

Methyl 4-fluoropicolinate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to fluorinated heterocycles and bioactive scaffolds. Its electron-deficient pyridine ring facilitates nucleophilic substitution and transition-metal-catalyzed coupling reactions. The methyl ester group offers straightforward derivatization, while the fluorine substituent provides favorable electronic effects and metabolic stability, making it valuable for medicinal chemistry and agrochemical research.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 39.19
LogP 1.0073
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 4-fluoropicolinate

CAS No. 886371-79-5

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