Methyl 1-bromo-2-naphthoate

Name: Methyl 1-bromo-2-naphthoate
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CAS No. 89555-39-5
Cat. No. CS-0310642
Purity≥98%
MDL No.MFCD06203695

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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Description

Methyl 1-bromo-2-naphthoate features a bromine atom at the 1-position of the naphthalene core, enabling direct functionalization in cross-coupling reactions. The ester group provides solubility in common organic solvents and serves as a handle for subsequent derivatization. This compound offers high reactivity and stability under standard bench conditions.

Application

Methyl 1-bromo-2-naphthoate serves as a versatile building block in synthetic organic chemistry, enabling palladium-catalyzed cross-coupling reactions due to its well-defined bromo functionality. The naphthoate ester moiety provides compatibility with standard deprotection and functionalization protocols, while the molecule exhibits good bench stability and ease of purification. It functions reliably in the construction of biaryl scaffolds and complex heterocycles relevant to pharmaceutical and materials synthesis.

General Information

CAS No. 89555-39-5
Cat. No. CS-0310642
Purity ≥98%
MDL No. MFCD06203695
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₉BrO₂
Molecular Weight 265.10
Synonym(s) Naphthalenecarboxylic acid, 1-bromo-, methyl ester
SMILES O=C(C1=CC=C2C=CC=CC2=C1Br)OC

Computational Chemistry Data

TPSA 26.3
LogP 3.3889
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Naphthalene compounds

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Methyl 1-bromo-2-naphthoate

CAS No. 89555-39-5

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