2,2'-Bis(trifluoromethyl)-[1,1'-biphenyl]-4,4'-dicarboxylic acid

Name: 2,2'-Bis(trifluoromethyl)-[1,1'-biphenyl]-4,4'-dicarboxylic acid
Brand: ChemScene
Availability: InStock
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CAS No. 89803-71-4
Cat. No. CS-0187911
Purity≥95%
MDL No.MFCD30533922

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2,2'-Bis(trifluoromethyl)-[1,1'-biphenyl]-4,4'-dicarboxylic acid|CS-0187911

Structure of 89803-71-4

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General Information

CAS No. 89803-71-4
Cat. No. CS-0187911
Purity ≥95%
MDL No. MFCD30533922
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₆H₈F₆O₄
Molecular Weight 378.23
Synonym(s) None
SMILES O=C(O)C=1C=CC(C2=CC=C(C=C2C(F)(F)F)C(=O)O)=C(C1)C(F)(F)F

Description

This biphenyl-based dicarboxylic acid features two trifluoromethyl groups at the ortho positions of each phenyl ring, imparting high electron deficiency and enhanced stability. The rigid, planar architecture supports efficient π-stacking, while the carboxylic acid functionalities enable straightforward coupling in metal-organic framework synthesis and conjugated polymer design under standard conditions.

Application

2,2'-Bis(trifluoromethyl)-[1,1'-biphenyl]-4,4'-dicarboxylic acid serves as a versatile building block for the synthesis of functionalized aromatic scaffolds and metal-organic frameworks. Its dual carboxylic acid groups enable efficient coupling reactions, while the electron-withdrawing trifluoromethyl substituents enhance stability and modulate electronic properties. The compound exhibits excellent bench stability and facilitates straightforward purification, making it well-suited for iterative synthetic workflows in medicinal chemistry and materials science.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 74.6
LogP 4.7876
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 3

Other Classifications

Building Blocks Functional Group Fluoride

Building Blocks Functional Group Carboxylic Acid

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Key Words

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2,2'-Bis(trifluoromethyl)-[1,1'-biphenyl]-4,4'-dicarboxylic acid

CAS No. 89803-71-4

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