1,10-Phenanthroline-5-carbaldehyde

Name: 1,10-Phenanthroline-5-carbaldehyde
Brand: ChemScene
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CAS No. 91804-75-0
Cat. No. CS-W004559
Purity≥95%
MDL No.MFCD20528237

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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1,10-Phenanthroline-5-carbaldehyde|CS-W004559

Structure of 91804-75-0

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General Information

CAS No. 91804-75-0
Cat. No. CS-W004559
Purity ≥95%
MDL No. MFCD20528237
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₃H₈N₂O
Molecular Weight 208.22
Synonym(s) 5-carboxaldehyde
SMILES O=CC1=CC(C=CC=N2)=C2C3=C1C=CC=N3

Description

1,10-Phenanthroline-5-carbaldehyde features a rigid polycyclic scaffold with a strategically positioned aldehyde group at the 5-position. This configuration enables efficient coordination to metal centers while offering a reactive handle for conjugation via imine formation or reductive amination. The molecule exhibits enhanced solubility in polar organic solvents and maintains stability under ambient conditions, facilitating its use in transition metal catalysis and ligand design.

Application

1,10-Phenanthroline-5-carbaldehyde serves as a versatile ligand scaffold in transition metal catalysis and coordination chemistry. The aldehyde functionality enables facile derivatization via reductive amination or Wittig-type transformations, while the rigid phenanthroline core provides strong chelation to metals such as copper, ruthenium, and iron. Its bench-stable nature and compatibility with diverse reaction conditions make it a practical building block for functionalized ligands and heterocyclic frameworks in synthetic and materials applications.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 42.85
LogP 2.5955
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Key Words

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1,10-Phenanthroline-5-carbaldehyde

CAS No. 91804-75-0

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