3-Bromo-biphenyl-4-ol

Name: 3-Bromo-biphenyl-4-ol
Brand: ChemScene
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CAS No. 92-03-5
Cat. No. CS-0070364
Purity≥98%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 92-03-5

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Description

3-Bromo-biphenyl-4-ol features a bromine substituent at the 3-position and a phenolic hydroxyl group at the 4-position of a biphenyl scaffold. This configuration enables direct functionalization in cross-coupling reactions while maintaining stability under standard conditions. The electron-rich aromatic system facilitates efficient transition metal catalysis, and the hydroxyl group provides a handle for further derivatization or protection.

Application

3-Bromo-biphenyl-4-ol serves as a versatile building block in cross-coupling reactions, enabling efficient construction of biaryl scaffolds under palladium catalysis. The phenolic hydroxyl group provides orthogonal reactivity for derivatization, while the bromo substituent offers high compatibility with Suzuki, Stille, and Negishi coupling protocols. Bench-stable and readily purified by recrystallization, it functions reliably in medicinal chemistry and materials synthesis workflows.

General Information

CAS No. 92-03-5
Cat. No. CS-0070364
Purity ≥98%
MDL No. None
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₉BrO
Molecular Weight 249.10
Synonym(s) 3-BROMO-4-HYDROXYDIPHENYL
SMILES BrC1=CC(C2=CC=CC=C2)=CC=C1O

Computational Chemistry Data

TPSA 20.23
LogP 3.8217
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

Quality Control

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Bromo-biphenyl-4-ol

CAS No. 92-03-5

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