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CS-W001157 4
Total: USD 88.00

Thianthrene

  • CAS No. 92-85-3

  • Cat. No. CS-W014836
  • Molecule weight216.33
  • Purity≥98%
  • MDL No.MFCD00005065

*For research and further manufacturing use only, not for direct human use.

Thianthrene|CS-W014836

Structure of 92-85-3

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General Information

  • CAS No. 92-85-3
  • Cat. No. CS-W014836
  • Purity ≥98%
  • MDL No. MFCD00005065
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₂H₈S₂
  • Molecular Weight 216.33
  • Synonym(s) None
  • SMILES C12=CC=CC=C1SC3=C(C=CC=C3)S2

Description

Thianthrene undergoes liquid phase tert-butylation in the presence of large pore zeolites and mesoporous aluminosilicates catalyst to yield tert-butyl derivatives. Thianthrene on oxidation in the presence of hydrogen peroxide and ligninase as catalyst from Phanerochaete chrysosporium yields thianthrene monosulfoxide.Thianthrene has been used to study aqueous solubilities of several solid nitrogen-, sulfur- and oxygen-containing heterocyclic derivatives of anthracene, phenanthrene and fluorene. It has been used in determination of partition coefficients of several sulfur-containing aromatics in 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and supercritical carbon dioxide.

Synthesis

  • Route1

    References

    • Morita, Hiroyuki; Oida, Yasutaka; Ariga, Takamine; Fukumoto, Satoru; Sheikh, Md. Chanmiya; Fujii, Takayoshi; Yoshimura, Toshiaki Tetrahedron, 2011 , vol. 67, # 25 p. 4672 - 4679
  • Route2

    References

    • Bhatt, Vivekananda M.; Babu, Ramesh J. Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1988 , vol. 27, # 1-12 p. 259 - 260
  • Route3
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      71-43-2
    • ~%
    • In-stock
      Thianthrene|CS-W014836
      92-85-3

    References

    • Annales de Chimie (Cachan, France), , vol. <6> 1, p. 530 Annales de Chimie (Cachan, France), , vol. 14, p. 441 Chemische Berichte, , vol. 29, p. 437 Recueil des Travaux Chimiques des Pays-Bas, , vol. 24, p. 217 Bulletin de la Societe Chimique de France, , vol. <3> 15, p. 409

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   4.3024
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   0

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