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CS-W001157 4
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2,4,6-Ethenylboroxin-pyridine complex,98%(stabilized with TBC)

  • CAS No. 95010-17-6

  • Cat. No. CS-0016522
  • Purity≥97%
  • MDL No.MFCD03839940

*For research and further manufacturing use only, not for direct human use.

2,4,6-Ethenylboroxin-pyridine complex,98%(stabilized with TBC)|CS-0016522

Structure of 95010-17-6

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General Information

  • CAS No. 95010-17-6
  • Cat. No. CS-0016522
  • Purity ≥97%
  • MDL No. MFCD03839940
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₁H₁₄B₃NO₃
  • Molecular Weight 240.67
  • Synonym(s) Trivinylcyclotriboroxane pyridine complex; Vinylboronic anhydride pyridine complex; Trivinylcyclotriboroxan - Pyridine Complex
  • SMILES C=CB1(OB(OB(O1)C=C)C=C)[N]2=CC=CC=C2

Description

The 2,4,6-ethenylboroxin-pyridine complex offers a bench-stable, moisture-tolerant boron source for cross-coupling reactions. This stabilized form integrates seamlessly into palladium-catalyzed transformations, delivering efficient coupling with aryl and vinyl partners under mild conditions.

Application

The 2,4,6-ethenylboroxin-pyridine complex, stabilized with TBC, serves as a bench-stable boron source for Suzuki-Miyaura cross-coupling reactions. Its pyridine coordination enhances solubility and reactivity while minimizing protodeboronation. The ethenylboroxin moiety enables efficient coupling with aryl and vinyl halides, facilitating the construction of conjugated olefinic architectures with high functional group tolerance and predictable regiochemistry.

Synthesis

  • Route1
    • null|null
      110-86-1
    • Vinylboronic acid|CS-0176836
      4363-34-2
    • ~%
    • In-stock
      2,4,6-Ethenylboroxin-pyridine complex,98%(stabilized with TBC)|CS-0016522
      95010-17-6

    References

    • US2004/6245 A1, ; Page 25 ;

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS07
Signal Word : Danger
UN#: 1325
Class : 4.1
Packing Group : Ⅲ
Hazard Statements : H228-H302+H312+H332-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362-P370+P378-P501

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Computational Chemistry Data

  • TPSA   N/A
  • LogP   N/A
  • H_Acceptors   N/A
  • H_Donors   N/A
  • Rotatable_Bonds   N/A

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