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CS-W001157 4
Total: USD 88.00

[Ir(Cp-)Cl2]2

  • CAS No. 12354-84-6

  • Cat. No. CS-0022677
  • Molecule weight796.70
  • Purity≥98%
  • MDL No.MFCD00075435

*For research and further manufacturing use only, not for direct human use.

[Ir(Cp-)Cl2]2|CS-0022677

Structure of 12354-84-6

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General Information

  • CAS No. 12354-84-6
  • Cat. No. CS-0022677
  • Purity ≥98%
  • MDL No. MFCD00075435
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₀H₃₀Cl₄Ir₂
  • Molecular Weight 796.70
  • Synonym(s) Pentamethylcyclopentadienyliridium(III) chloride,dimer
  • SMILES Cc1c(C)c(C)c(C)c1C.Cc2c(C)c(C)c(C)c2C.C[Ir]3(Cl[Ir](Cl)(C)Cl3)Cl.C

Description

Pentamethylcyclopentadienyliridium(III) chloride, dimer is utilized as a catalyst in cross-coupling and dimerization reactions.We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.Catalyst for greener amine synthesis from amines and alcohols by hydrogen-borrowing. Precursor to cooperative metal-Bronsted acid catalyst for greener reductive amination using hydrogen gas.Metal-Brnsted Acid Cooperative Catalysis for Asymmetric Reductive AminationDevelopment of GSK's reagent guides embedding sustainability into reagent selection

Synthesis

  • Route1
    • (L-Aspartato)(η5-pentamethylcyclopentdienyl)iridium(III)|CS-0636460
      124155-06-2
    • ~0%
    • In-stock
      [Ir(Cp-)Cl2]2|CS-0022677
      12354-84-6
    • null|null
      124155-05-1

    References

    • Kraemer, Roland; Polborn, Kurt; Wanjek, Herbert; Zahn, Ingo; Beck, Wolfgang Chemische Berichte, 1990 , vol. 123, # 4 p. 767 - 778
  • Route2
    • Dichloro(methanamine)[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]iridium,|CS-0213853
      1071750-85-0
    • ~%
    • In-stock
      [Ir(Cp-)Cl2]2|CS-0022677
      12354-84-6

    References

    • Inorganic Chemistry, , vol. 47, # 20 p. 9592 - 9605
  • Route3
    • null|null
      1071750-86-1
    • ~%
    • In-stock
      [Ir(Cp-)Cl2]2|CS-0022677
      12354-84-6

    References

    • Inorganic Chemistry, , vol. 47, # 20 p. 9592 - 9605

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS07,GHS08
Signal Word : Danger
UN#: 1325
Class : 4.1
Packing Group : Ⅲ
Hazard Statements : H228-H302-H305-H315-H317-H320-H402
Precautionary Statements : P210-P264-P280-P402+P404-P501

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Computational Chemistry Data

  • TPSA   N/A
  • LogP   N/A
  • H_Acceptors   N/A
  • H_Donors   N/A
  • Rotatable_Bonds   N/A

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