Methyl 4-bromo-5-methoxypicolinate

CAS No. 1256803-62-9
Cat. No. CS-0145977
Molecule weight246.06
Purity≥98%
MDL No.None

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Methyl 4-bromo-5-methoxypicolinate|CS-0145977

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General Information

CAS No. 1256803-62-9
Cat. No. CS-0145977
Purity ≥98%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₈BrNO₃
Molecular Weight 246.06
Synonym(s) Methyl 4-bromo-5-methoxy-2-pyridinecarboxylate
SMILES O=C(C1=NC=C(OC)C(Br)=C1)OC

Description

Methyl 4-bromo-5-methoxypicolinate is a versatile pyridine-based building block featuring a bromine atom at the 4-position and a methoxy group at the 5-position. This electronic configuration enables selective cross-coupling reactions, while the methyl ester facilitates downstream derivatization. The molecule exhibits excellent stability under standard handling conditions and integrates readily into complex synthetic sequences.

Application

Methyl 4-bromo-5-methoxypicolinate serves as a versatile building block in heterocyclic synthesis, enabling palladium-catalyzed cross-coupling reactions due to its well-defined bromine functionality. The methoxy group enhances solubility and modulates reactivity, while the ester moiety supports further transformations such as hydrolysis or reduction. Its bench-stable nature and compatibility with standard reaction conditions make it ideal for constructing complex scaffolds in medicinal chemistry and agrochemical research.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 48.42
LogP 1.6393
H_Acceptors 4
H_Donors 0
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 4-bromo-5-methoxypicolinate

CAS No. 1256803-62-9

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