6-Bromo-2-oxaspiro[3.3]heptane

CAS No. 1363380-78-2
Cat. No. CS-0050289
Molecule weight177.04
Purity≥97%
MDL No.None

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FedEx Limited Quantities Ground	$0.00
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6-Bromo-2-oxaspiro[3.3]heptane|CS-0050289

Structure of 1363380-78-2

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General Information

CAS No. 1363380-78-2
Cat. No. CS-0050289
Purity ≥97%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₉BrO
Molecular Weight 177.04
Synonym(s) 6-BroMo-2-oxa-spiro[3.3]heptane
SMILES BrC1CC2(COC2)C1

Description

6-Bromo-2-oxaspiro[3.3]heptane features a rigid spirocyclic core with a bromine substituent at the bridgehead position, enabling direct functionalization in synthetic sequences. The oxetane ring imparts high strain energy, facilitating ring-opening reactions under mild conditions. This scaffold serves as a valuable building block for complex heterocycles and bioactive molecule synthesis.

Application

6-Bromo-2-oxaspiro[3.3]heptane serves as a versatile spirocyclic building block in synthetic organic chemistry, enabling efficient access to complex heterocyclic architectures. The bromine substituent facilitates palladium-catalyzed cross-coupling reactions, while the rigid spirocyclic framework imparts conformational stability and enhances functional group tolerance. Its bench-stable nature and compatibility with standard reaction conditions make it well-suited for iterative synthesis and medicinal chemistry applications.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 9.23
LogP 1.5603
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Skeleton Aliphatic heterocycle compounds Oxetane compounds

Building Blocks Skeleton Fatty ring compounds Cyclobutane compounds

Building Blocks Skeleton Spirol Rings compounds

Key Words

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6-Bromo-2-oxaspiro[3.3]heptane

CAS No. 1363380-78-2

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