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CS-W001157 4
Total: USD 88.00

DMTMM

  • CAS No. 3945-69-5

  • Cat. No. CS-0017161
  • Molecule weightNone
  • Purity97% (contains <17%H2O)
  • MDL No.MFCD03613550

*For research and further manufacturing use only, not for direct human use.

DMTMM|CS-0017161

Structure of 3945-69-5

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General Information

  • CAS No. 3945-69-5
  • Cat. No. CS-0017161
  • Purity 97% (contains <17%H2O)
  • MDL No. MFCD03613550
  • Storage 4°C, sealed storage, away from moisture
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₁₇ClN₄O₃
  • Molecular Weight None
  • Synonym(s) 4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride
  • SMILES C[N+]1(C2=NC(OC)=NC(OC)=N2)CCOCC1.[Cl-]

Description

4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride can be used as a condensing agent for the following transformations:Condensation of carboxylic acids and amines to the corresponding amides in tetrahydrofuran.Esterification of carboxylic acids with alcohols to the corresponding esters.Conversion of carboxylic acids to the corresponding Weinreb amides in protic solvents.

Synthesis

  • Route1

    References

    • Hirano, Naoki; Saijyo, Masako Patent: US2003/153785 A1, 2003 ;
  • Route2
    • null|null
      109-02-4
    • In-stock
      Chlorodimethoxytriazine|CS-W017434
      3140-73-6
    • ~99%
    • In-stock
      DMTMM|CS-0017161
      3945-69-5

    References

    • Kolesinska, Beata; Kasperowicz, Katarzyna; Sochacki, Marek; Mazur, Adam; Jankowski, Stefan; Kaminski, Zbigniew J. Tetrahedron Letters, 2010 , vol. 51, # 1 p. 20 - 22
  • Route3
    • null|null
      109-02-4
    • In-stock
      Chlorodimethoxytriazine|CS-W017434
      3140-73-6
    • null|null
      107-92-6
    • ~%
    • null|null
      1423116-02-2
    • In-stock
      DMTMM|CS-0017161
      3945-69-5

    References

    • Kunishima, Munetaka; Ujigawa, Takae; Nagaoka, Yoshie; Kawachi, Chiho; Hioki, Kazuhito; Shiro, Motoo Chemistry - A European Journal, 2012 , vol. 18, # 49 p. 15856 - 15867

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05,GHS07
Signal Word : Danger
UN#: 3261
Class : 8
Packing Group : Ⅱ
Hazard Statements : H302-H314
Precautionary Statements : P260-P264-P270-P280-P301+P330+P331-P304+P340-P330-P363-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   66.36
  • LogP   -3.1399
  • H_Acceptors   6
  • H_Donors   0
  • Rotatable_Bonds   3

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