1-Bromo-4-phenoxybenzene

Name: 1-Bromo-4-phenoxybenzene
Brand: ChemScene
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CAS No. 101-55-3
Cat. No. CS-M1054
Purity≥97%
MDL No.MFCD00000094

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 101-55-3

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Description

1-Bromo-4-phenoxybenzene features a phenoxy substituent positioned para to a bromine atom on an aromatic ring, enabling selective coupling reactions in pharmaceutical synthesis. This electron-deficient aryl halide exhibits enhanced stability and compatibility with palladium-catalyzed cross-coupling protocols under standard conditions.

Application

1-Bromo-4-phenoxybenzene serves as a versatile aryl halide building block in palladium-catalyzed cross-coupling reactions, enabling efficient C–C bond formation under standard Suzuki, Stille, and Negishi conditions. Its phenoxy substituent provides enhanced solubility and stability compared to non-substituted analogs, while the bromine functionality offers predictable reactivity with broad functional group tolerance. This compound is particularly useful for constructing biaryl scaffolds found in agrochemicals and advanced materials.

General Information

CAS No. 101-55-3
Cat. No. CS-M1054
Purity ≥97%
MDL No. MFCD00000094
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₉BrO
Molecular Weight 249.11
Synonym(s) p-Bromodiphenyl ether; 4-Bromophenoxybenzene
SMILES BrC1=CC=C(C=C1)OC2=CC=CC=C2

Computational Chemistry Data

TPSA 9.23
LogP 4.2414
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 2

Safety Information

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GHS Pictogram :	GHS No : GHS05,GHS07,GHS09
Signal Word : Danger	UN#: 3082
Class : 9	Packing Group : Ⅲ
Hazard Statements : H302-H317-H318-H410
Precautionary Statements : P261-P264-P270-P272-P273-P280-P302+P352-P330-P362+P364-P391-P501

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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1-Bromo-4-phenoxybenzene

CAS No. 101-55-3

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