Lot numbers can be found on the outside label of a product:
2-Bromo-4-methoxypyridin-3-amine
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CAS No. 109613-97-0
- Cat. No. CS-0018837
- Purity≥95%
- MDL No.MFCD11044243
*For research and further manufacturing use only, not for direct human use.
Structure of 109613-97-0
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General Information
- CAS No. 109613-97-0
- Cat. No. CS-0018837
- Purity ≥95%
- MDL No. MFCD11044243
- Storage 4°C, protect from light, stored under nitrogen
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₆H₇BrN₂O
- Molecular Weight 203.04
- Synonym(s) (2-Bromo-4-methoxypyridin-3-yl)amine; 2-Bromo-4-methoxypyridin-3-amine; 3-Amino-2-bromo-4-methoxypyridine
- SMILES NC1=C(OC)C=CN=C1Br
Description
2-Bromo-4-methoxypyridin-3-amine features a pyridine core bearing bromo, methoxy, and amino groups at the 2-, 4-, and 3-positions respectively, enabling selective coupling in cross-coupling reactions. The electron-rich aromatic system supports efficient palladium-catalyzed transformations, while the methoxy group enhances solubility and modulates reactivity. This bench-stable intermediate facilitates rapid access to complex heterocyclic scaffolds in medicinal chemistry.
Application
2-Bromo-4-methoxypyridin-3-amine serves as a versatile building block in medicinal chemistry, enabling palladium-catalyzed cross-coupling reactions due to its well-defined electrophilic bromide and nucleophilic amine functionality. The methoxy group enhances solubility and modulates electronic properties, while the compound exhibits excellent bench stability and compatibility with standard reaction conditions, facilitating efficient synthesis of pyridine-based scaffolds.
Synthesis
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Route1
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In-stock
33631-09-3 - ~80%
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In-stock
109613-97-0
References
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SANOFI; CHOI-SLEDESKI, Yong Mi; NIEDUZAK, Thaddeus R.; POLI, Gregory B.; SHUM, Patrick Wai-Kwok; STOKLOSA, Gregory T.; ZHAO, Zhicheng Patent: WO2011/78984 A1, 2011 ; Location in patent: Page/Page column 62; 63 ; WO 2011/078984 A1
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Route2
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In-stock
31872-62-5 - ~%
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In-stock
109613-97-0
References
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SANOFI; CHOI-SLEDESKI, Yong Mi; NIEDUZAK, Thaddeus R.; POLI, Gregory B.; SHUM, Patrick Wai-Kwok; STOKLOSA, Gregory T.; ZHAO, Zhicheng Patent: WO2011/78984 A1, 2011 ; WO 2011/078984 A1
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Route3
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In-stock
620-08-6 - ~%
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In-stock
109613-97-0
References
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SANOFI; CHOI-SLEDESKI, Yong Mi; NIEDUZAK, Thaddeus R.; POLI, Gregory B.; SHUM, Patrick Wai-Kwok; STOKLOSA, Gregory T.; ZHAO, Zhicheng Patent: WO2011/78984 A1, 2011 ; WO 2011/078984 A1
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 48.14
- LogP 1.4349
- H_Acceptors 3
- H_Donors 1
- Rotatable_Bonds 1
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Key Words
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