4'-Methoxy-[1,1'-biphenyl]-4-amine

Name: 4'-Methoxy-[1,1'-biphenyl]-4-amine
Brand: ChemScene
Availability: InStock
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CAS No. 1137-77-5
Cat. No. CS-0199547
Purity≥96%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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4'-Methoxy-[1,1'-biphenyl]-4-amine|CS-0199547

Structure of 1137-77-5

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Description

4'-Methoxy-[1,1'-biphenyl]-4-amine features a para-methoxy group enhancing electron density at the terminal phenyl ring, enabling efficient coupling in Pd-catalyzed cross-coupling reactions. The amine functionality provides a robust handle for derivatization and incorporation into functional materials. This compound exhibits good stability under standard bench conditions and demonstrates favorable solubility in common organic solvents.

Application

4'-Methoxy-[1,1'-biphenyl]-4-amine serves as a versatile building block in medicinal chemistry and materials science, enabling efficient construction of biaryl scaffolds via palladium-catalyzed cross-coupling reactions. The ortho-methoxy and para-amino groups provide complementary reactivity for sequential functionalization, while the biphenyl core offers rigidity and π-conjugation. Bench-stable and readily purified by recrystallization, it functions effectively in standard amide coupling, Suzuki-Miyaura, and electrophilic substitution protocols.

General Information

CAS No. 1137-77-5
Cat. No. CS-0199547
Purity ≥96%
MDL No. None
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₃H₁₃NO
Molecular Weight 199.25
Synonym(s) 4'-Methoxy-biphenyl-4-amine
SMILES COC1=CC=C(C=C1)C2=CC=C(C=C2)N

Computational Chemistry Data

TPSA 35.25
LogP 2.9444
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 2

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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4'-Methoxy-[1,1'-biphenyl]-4-amine

CAS No. 1137-77-5

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