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CS-W001157 4
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AdBrettPhos

  • CAS No. 1160861-59-5

  • Cat. No. CS-0085964
  • Molecule weight640.92
  • Purity≥97%
  • MDL No.MFCD23379935

*For research and further manufacturing use only, not for direct human use.

AdBrettPhos|CS-0085964

Structure of 1160861-59-5

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General Information

  • CAS No. 1160861-59-5
  • Cat. No. CS-0085964
  • Purity ≥97%
  • MDL No. MFCD23379935
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₄₃H₆₁O₂P
  • Molecular Weight 640.92
  • Synonym(s) Di(adamantan-1-yl)(2',4',6'-triisopropyl-3,6-dimethoxy-2-biphenyl yl)phosphine
  • SMILES COC1=C(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)C(P(C34C[C@@H]5C[C@H](C4)C[C@H](C3)C5)C6(C[C@H]7C8)C[C@@H](C7)C[C@@H]8C6)=C(OC)C=C1

Synthesis

  • Route1
    • 2-Iodo-2',4',6'-triisopropyl-3,6-dimethoxy-1,1'-biphenyl|CS-0685573
      1070663-76-1
    • Di(1-adaMantyl)chlorophosphine|CS-0106422
      157282-19-4
    • ~%
    • In-stock
      AdBrettPhos|CS-0085964
      1160861-59-5

    References

    • Su, Mingjuan; Buchwald, Stephen L. Angewandte Chemie - International Edition, 2012 , vol. 51, # 19 p. 4710 - 4713
  • Route2

    References

    • Su, Mingjuan; Buchwald, Stephen L. Angewandte Chemie - International Edition, 2012 , vol. 51, # 19 p. 4710 - 4713

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS05,GHS06,GHS09
Signal Word : Danger
UN#: 1325
Class : 4.1
Packing Group : Ⅱ
Hazard Statements : H225-H301+H331-H314-H335-H400
Precautionary Statements : P210-P233-P240-P241-P242-P243-P260-P261-P264-P270-P271-P273-P280-P301+P330+P331-P304+P340-P330-P363-P370+P378-P391-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   18.46
  • LogP   11.7858
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   9

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