2-Chloro-6-methylbenzaldehyde

Name: 2-Chloro-6-methylbenzaldehyde
Brand: ChemScene
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CAS No. 1194-64-5
Cat. No. CS-0043396
Purity≥97%
MDL No.MFCD01934409

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2-Chloro-6-methylbenzaldehyde|CS-0043396

Structure of 1194-64-5

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Description

2-Chloro-6-methylbenzaldehyde features a chlorinated aromatic ring with a methyl group at the para position relative to the aldehyde. This electron-deficient benzaldehyde integrates readily into Suzuki and Ullmann coupling reactions, offering enhanced reactivity under standard conditions. The ortho-chloro substituent imparts steric and electronic control, enabling selective functionalization in complex synthesis.

Application

2-Chloro-6-methylbenzaldehyde serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling direct functionalization at the aromatic ring due to its ortho-chloro and methyl substituents. The aldehyde group facilitates efficient imine formation, reductive amination, and coupling reactions, while the chloro and methyl groups offer predictable electronic and steric modulation. Its bench-stable nature and compatibility with standard synthetic protocols make it ideal for multi-step synthesis and process development.

General Information

CAS No. 1194-64-5
Cat. No. CS-0043396
Purity ≥97%
MDL No. MFCD01934409
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₇ClO
Molecular Weight 154.59
Synonym(s) 3-Chloro-2-formyltoluene
SMILES O=CC1=C(C)C=CC=C1Cl

Computational Chemistry Data

TPSA 17.07
LogP 2.46092
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

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Other Classifications

Building Blocks Functional Group Aldehyde

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Chloro-6-methylbenzaldehyde

CAS No. 1194-64-5

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