Methyl 5-bromo-6-fluoropicolinate

Name: Methyl 5-bromo-6-fluoropicolinate
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CAS No. 1214336-44-3
Cat. No. CS-0312388
Purity≥95%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Methyl 5-bromo-6-fluoropicolinate|CS-0312388

Structure of 1214336-44-3

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Description

Methyl 5-bromo-6-fluoropicolinate is a fluorinated heterocyclic ester featuring complementary halogen substituents at the 5 and 6 positions of the picolinate core. This electron-deficient scaffold enables selective cross-coupling reactions under palladium catalysis, offering high functional group tolerance. The methyl ester facilitates downstream derivatization while maintaining stability under standard bench conditions.

Application

Methyl 5-bromo-6-fluoropicolinate serves as a versatile building block for heterocyclic synthesis, enabling palladium-catalyzed cross-coupling reactions due to its orthogonal halogen reactivity. The bromo and fluoro substituents provide complementary sites for sequential functionalization, while the methyl ester facilitates downstream transformations. This compound exhibits excellent bench stability and is compatible with standard reaction conditions in medicinal chemistry and process development workflows.

General Information

CAS No. 1214336-44-3
Cat. No. CS-0312388
Purity ≥95%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₅BrFNO₂
Molecular Weight 234.02
Synonym(s) methyl 5-bromo-6-fluoro-pyridine-2-carboxylate
SMILES O=C(C1=NC(F)=C(Br)C=C1)OC

Computational Chemistry Data

TPSA 39.19
LogP 1.7698
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H312-H315-H319-H332-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Drug Discovery Cancer PARP

Key Words

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Methyl 5-bromo-6-fluoropicolinate

CAS No. 1214336-44-3

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