3,8-Bis[3,5-bis(trifluoromethyl)phenyl]-1,10-phenanthroline

Name: 3,8-Bis[3,5-bis(trifluoromethyl)phenyl]-1,10-phenanthroline
Brand: ChemScene
Availability: InStock
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CAS No. 1228032-35-6
Cat. No. CS-0088160
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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3,8-Bis[3,5-bis(trifluoromethyl)phenyl]-1,10-phenanthroline|CS-0088160

Structure of 1228032-35-6

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Description

This 3,8-bis[3,5-bis(trifluoromethyl)phenyl]-1,10-phenanthroline features a sterically shielded, electron-deficient ligand framework with enhanced stability and strong metal-chelating capacity. The trifluoromethyl groups confer high hydrophobicity and resistance to oxidation, enabling robust coordination in catalytic systems. This phenanthroline derivative delivers exceptional performance in transition-metal complexes under demanding reaction conditions.

Application

3,8-Bis[3,5-bis(trifluoromethyl)phenyl]-1,10-phenanthroline serves as a sterically hindered, electron-deficient bidentate ligand that facilitates transition metal catalysis in cross-coupling and oxidation reactions. Its perfluorinated aryl substituents enhance oxidative stability and promote π-stacking interactions in coordination complexes, enabling efficient catalyst turnover in Pd- and Cu-mediated transformations. The ligand exhibits excellent bench stability and simplifies purification due to high solubility in common organic solvents.

General Information

CAS No. 1228032-35-6
Cat. No. CS-0088160
Purity ≥97%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₈H₁₂F₁₂N₂
Molecular Weight 604.39
Synonym(s) 3,8-Bis[{3,5-bis(trifluoromethyl)}phenyl]-1,10-phenanthroline
SMILES FC(F)(F)C1=CC(C(F)(F)F)=CC(C(C=N2)=CC3=C2C(N=CC(C4=CC(C(F)(F)F)=CC(C(F)(F)F)=C4)=C5)=C5C=C3)=C1

Computational Chemistry Data

TPSA 25.78
LogP 10.1922
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 2

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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3,8-Bis[3,5-bis(trifluoromethyl)phenyl]-1,10-phenanthroline

CAS No. 1228032-35-6

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