2,9-Dibromo-1,10-phenanthroline

Name: 2,9-Dibromo-1,10-phenanthroline
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 39069-02-8
Cat. No. CS-W004597
Purity≥95%
MDL No.MFCD16038623

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2,9-Dibromo-1,10-phenanthroline|CS-W004597

Structure of 39069-02-8

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Description

2,9-Dibromo-1,10-phenanthroline features two bromine substituents at the 2 and 9 positions of the phenanthroline scaffold, enhancing its electron-deficient character and enabling robust coordination with transition metals. This sterically defined ligand delivers stable complexes in catalytic systems and facilitates selective metal binding under standard conditions.

Application

2,9-Dibromo-1,10-phenanthroline serves as a versatile chelating ligand in transition metal catalysis, offering enhanced electronic modulation through bromine substitution at the 2 and 9 positions. Its stability under standard reaction conditions facilitates efficient coordination to metals such as palladium and copper, enabling its use in cross-coupling reactions and C–H functionalization protocols. The bromo groups provide handles for further derivatization, enhancing utility in the construction of complex heterocyclic scaffolds and functionalized ligands.

General Information

CAS No. 39069-02-8
Cat. No. CS-W004597
Purity ≥95%
MDL No. MFCD16038623
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₆Br₂N₂
Molecular Weight 338.00
Synonym(s) 2_9-dibromo-1,10-phenanthroline
SMILES BrC1=NC2=C3C(C=CC(Br)=N3)=CC=C2C=C1

Computational Chemistry Data

TPSA 25.78
LogP 4.308
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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2,9-Dibromo-1,10-phenanthroline

CAS No. 39069-02-8

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