7-Bromo-1-methyl-1H-benzo[d]imidazole

Name: 7-Bromo-1-methyl-1H-benzo[d]imidazole
Brand: ChemScene
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CAS No. 1233542-00-1
Cat. No. CS-0097283
Purity≥97%
MDL No.MFCD23135915

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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7-Bromo-1-methyl-1H-benzo[d]imidazole|CS-0097283

Structure of 1233542-00-1

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Description

7-Bromo-1-methyl-1H-benzo[d]imidazole features a brominated benzene ring fused to a methylated imidazole core, delivering enhanced electron-withdrawing character and improved solubility in organic solvents. This scaffold enables efficient coupling reactions in transition-metal-catalyzed transformations, serving as a stable building block for bioactive heterocycles and functional materials.

Application

7-Bromo-1-methyl-1H-benzo[d]imidazole serves as a versatile building block in medicinal chemistry and heterocyclic synthesis. Its bromine substituent enables palladium-catalyzed cross-coupling reactions, while the methylated imidazole core provides enhanced stability and solubility. The compound functions effectively in Suzuki-Miyaura and Buchwald-Hartwig couplings, facilitating rapid access to complex biaryl and amine-containing scaffolds. Bench-stable and readily purified by recrystallization, it supports scalable synthesis of functionalized nitrogen heterocycles relevant to pharmaceutical development.

General Information

CAS No. 1233542-00-1
Cat. No. CS-0097283
Purity ≥97%
MDL No. MFCD23135915
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₇BrN₂
Molecular Weight 211.06
Synonym(s) 7-BroMo-1-Methylbenzodiazole
SMILES CN1C2=C(Br)C=CC=C2N=C1

Computational Chemistry Data

TPSA 17.82
LogP 2.3358
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Benzimidazole compounds

Key Words

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7-Bromo-1-methyl-1H-benzo[d]imidazole

CAS No. 1233542-00-1

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